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51.
Xian Suo Xili Cui Lifeng Yang Nan Xu Yuqi Huang Yi He Sheng Dai Huabin Xing 《Advanced materials (Deerfield Beach, Fla.)》2020,32(29):1907601
The design of highly stable and efficient porous materials is essential for developing breakthrough hydrocarbon separation methods based on physisorption to replace currently used energy-intensive distillation/absorption technologies. Efforts to develop advanced porous materials such as zeolites, coordination frameworks, and organic polymers have met with limited success. Here, a new class of ionic ultramicroporous polymers (IUPs) with high-density inorganic anions and narrowly distributed ultramicroporosity is reported, which are synthesized by a facile free-radical polymerization using branched and amphiphilic ionic compounds as reactive monomers. A covalent and ionic dual-crosslinking strategy is proposed to manipulate the pore structure of amorphous polymers at the ultramicroporous scale. The IUPs exhibit exceptional selectivity (286.1–474.4) for separating acetylene from ethylene along with high thermal and water stability, collaboratively demonstrated by gas adsorption isotherms and experimental breakthrough curves. Modeling studies unveil the specific binding sites for acetylene capture as well as the interconnected ultramicroporosity for size sieving. The porosity-engineering protocol used in this work can also be extended to the design of other ultramicroporous materials for the challenging separation of other key gas constituents. 相似文献
52.
安全壳泄漏率计算过程中,最重要的环节是以不同时刻测量数据对时间进行线性回归分析。对回归的显著性检验以及方差分析是评价试验结果有效性的重要手段。本文基于统计软件R对某电厂调试阶段安全壳泄漏率试验的数据进行分析,通过对线性回归模型的独立性、正态性和异方差性检验以及极端样本点的剔除等方式,探讨泄漏率计算前的回归诊断对计算结果可靠性的影响。通过回归诊断的实例分析发现,在安全壳泄漏率计算的数据样本中,可能存在自相关、非正态和异方差性等问题影响回归结果,进而影响泄漏率的最终结果。因此,在计算泄漏率结果时,须通过回归诊断方法评价数据的有效性,对不能通过检验的样本应通过适当方法对最终结果进行修正。 相似文献
53.
A series of single-component blue, green and red phosphors have been fabricated based on the Ca3Gd(GaO)3(BO3)4 host through doping of the Ce3+/Tb3+/Eu3+ ions, and their crystal structure and photoluminescence properties have been discussed in detail. A terbium bridge model via Ce3+ → Tb3+ → Eu3+ energy transfer has been studied. The emission colours of the phosphors can be tuned from blue (0.1661, 0.0686) to green (0.3263, 0.4791) and eventually to red (0.5284, 0.4040) under a single 344 nm UV excitation as the result of the Ce3+ → Tb3+ → Eu3+ energy transfer. The energy transfer mechanisms of Ce3+ → Tb3+ and Tb3+ → Eu3+ were found to be dipole-dipole interactions. Importantly, Ca3Gd(GaO)3(BO3)4:Ce3+,Tb3+,Eu3+ phosphors had high internal quantum efficiency. Moreover, the study on the temperature-dependent emission spectra revealed that the Ca3Gd(GaO)3(BO3)4:Ce3+,Tb3+,Eu3+ phosphors possessed good thermal stability. The above results indicate that the phosphors can be applied into white light-emitting diodes as single-component multi-colour phosphors. 相似文献
54.
针对二连盆地乌兰花凹陷安山岩储层的特性认识不清、有效储层划分不准确的问题,利用岩心薄片、黏土矿物分析、物性测试以及核磁共振实验等手段开展了岩石储集空间特征、岩石蚀变程度、测井响应特征分析。在此基础上,重点开展了基于核磁共振实验的安山岩储层有效孔隙度计算模型研究,开发了相适应的测井解释评价模块,并结合常规测井和试油结果建立了安山岩储层的分类标准。结果表明:安山岩储集空间具有发育"微孔"、"杏仁孔"双孔隙的特征,且以微孔为主;根据不同蚀变程度所建立的安山岩有效孔隙度计算模型具有很高的精度,平均绝对误差为0.16%,平均相对误差为19.40%;新测井解释储层分类标准在实际应用中与试油结论具有很好的一致性,有利于乌兰花凹陷安山岩有效储层的精确划分,并为该地区开发方案的设计及可采储量评价提供技术支持。 相似文献
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58.
Cheng-Feng Yue Shi-Jei Huang Jhewn-Kuang Chen Hsien-Tsung Li Kam-Shau Chan 《Metals and Materials International》2018,24(2):307-313
The effects of an addition of 0–2 wt% Nd on thermal stability of 0–3 wt% Ca-containing modified AZ71 magnesium alloys was investigated. The ignition temperature was found to increase from that of AZ71, 574, to 825 °C with the addition of 0.5 wt% Ca and 1 wt% Nd. The ignition temperature was further increased to 1114 °C when 3 wt% Ca was added. The Ca- and Nd-added AZ71 was isothermally maintained at a temperature of 500 °C in air for 12 h. The MgO–CaO–Nd2O3 formed on the surface to improve the thermal stability of the AZ71–xCa–yNd alloys. While both the tensile strength and ductility decreased with the Ca concentration in the alloy, an addition of 1 wt% Nd was found able to alleviate the degradation effects of Ca on the tensile strength and ductility at 170 °C. Both solid solution formation and precipitation strengthening contributed to the increase in toughness. AZ71 containing 0.5–2 wt% Ca and 1 wt% Nd provides the optimum combination of ignition resistance and mechanical properties. 相似文献
59.
Xiaoqing Si Jian Cao Sheng Liu Xiaoguo Song Junlei Qi Yongxian Huang Jicai Feng 《International Journal of Hydrogen Energy》2018,43(5):2977-2989
A novel low-temperature sealing method was developed to seal solid oxide fuel cells. The 3D Ni nanosheet array was pre-fabricated on faying surfaces of Crofer22APU interconnect and NiO-YSZ anode-support. Then it was covered with Au film without changing its morphology. This special nanostructure improved sintering efficiency between Ag nanoparticles and substrates. A dense joint was obtained at the low-temperature between 250 °C–300 °C. This method effectively avoided the oxidation of interconnect during sealing. When joints were sealed at 300 °C, the shear strength reached 16 MPa. The fracture was mainly located in the central Ag layer, presenting a significant plastic deformation. Due to the effective protection of Ni layer, joints also possessed excellent oxidation resistance in oxidizing atmosphere at 800 °C for 400 h. After high-temperature oxidation, the shear strength was increased to 23 MPa, revealing an increasement of 43.8% compared with the as-sealed condition (16 MPa). This sealing method has great potential in sealing solid oxide fuel cells. It also can be extended to seal other energy-conversion devices. 相似文献
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